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Issue 26, 2016
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Is the chemistry of lawrencium peculiar?

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Abstract

It is explicitly verified that the atomic 7p1 ground-state configuration of Lr originates from relativistic effects. Without relativity one has 6d1. All three ionization potentials IP1–3 of Lr resemble those of Lu. Simple model studies on mono- and trihydrides, monocarbonyls or trichlorides suggest no major chemical differences between Lr and the lanthanides.

Graphical abstract: Is the chemistry of lawrencium peculiar?

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Publication details

The article was received on 22 Apr 2016, accepted on 08 Jun 2016 and first published on 08 Jun 2016


Article type: Communication
DOI: 10.1039/C6CP02706G
Citation: Phys. Chem. Chem. Phys., 2016,18, 17351-17355
  • Open access: Creative Commons BY-NC license
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    Is the chemistry of lawrencium peculiar?

    W. Xu and P. Pyykkö, Phys. Chem. Chem. Phys., 2016, 18, 17351
    DOI: 10.1039/C6CP02706G

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