Issue 21, 2016

A CoII-based metal–organic framework based on [Co63-OH)4] units exhibiting selective sorption of C2H2 over CO2 and CH4

Abstract

By virtue of unique planar [Co63-OH)4] cluster units, a new microporous isonicotinate-based framework with high thermal and framework stabilities was achieved. The guest-free framework demonstrates high capacity and selectivity for C2H2 relative to CO2 and CH4 at room temperature, which was further understood by GCMC simulation.

Graphical abstract: A CoII-based metal–organic framework based on [Co6(μ3-OH)4] units exhibiting selective sorption of C2H2 over CO2 and CH4

Supplementary files

Article information

Article type
Communication
Submitted
30 Mar 2016
Accepted
19 Apr 2016
First published
03 May 2016

CrystEngComm, 2016,18, 3760-3763

A CoII-based metal–organic framework based on [Co63-OH)4] units exhibiting selective sorption of C2H2 over CO2 and CH4

D. Chen, J. Tian, C. Liu and M. Du, CrystEngComm, 2016, 18, 3760 DOI: 10.1039/C6CE00709K

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