Issue 38, 2016

Polymorphism driven optical properties of an anil dye

Abstract

Red crystals of N,N′-bis(3-methoxysalicylidene)-1,5-diiminonaphthalene were obtained after Schiff base condensation in ethanol. Recrystallization from acetone afforded yellow crystals, a process which is reversible and reproducible. Single crystal X-ray diffraction evidences two polymorphs differing in their space group and dihedral angle between aromatic moieties. DFT periodic calculations further confirmed the existence of two minima on the potential energy surface corresponding to red and yellow crystals. The red polymorph irreversibly (monotropically) transforms at 165–190 °C into the yellow one with a 3% increase of the unit cell volume, as shown by X-ray powder diffraction and periodic DFT calculations. Both polymorphs are thermochromic but only the red one displays photochromism upon irradiation at λ = 365 nm, which is reversible and exhibits a relatively slow thermal relaxation. A temperature induced cis/trans-keto equilibrium is for the first time identified for an N-salicylidene aniline derivative. Static DFT molecular and periodic calculations as well as ab initio Born–Oppenheimer dynamics simulations were performed to characterize the stability of both polymorphs and to determine the relative populations of the enol/cis-keto/trans-keto isomers at various temperatures.

Graphical abstract: Polymorphism driven optical properties of an anil dye

Supplementary files

Article information

Article type
Paper
Submitted
01 Feb 2016
Accepted
01 Mar 2016
First published
22 Mar 2016

CrystEngComm, 2016,18, 7249-7259

Polymorphism driven optical properties of an anil dye

D. A. Safin, K. Robeyns, M. G. Babashkina, Y. Filinchuk, A. Rotaru, C. Jureschi, M. P. Mitoraj, J. Hooper, M. Brela and Y. Garcia, CrystEngComm, 2016, 18, 7249 DOI: 10.1039/C6CE00266H

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