Issue 13, 2016
From the journal:

CrystEngComm

Characteristic redshift and intensity enhancement as far-IR fingerprints of the halogen bond involving aromatic donors†

Vera Vasylyeva,‡a   Luca Catalano,‡a   Carlo Nervi,b   Roberto Gobetto,b   Pierangelo Metrangolo*ac  and  Giuseppe Resnati*a  

* Corresponding authors

a Laboratory of Nanostructured Fluorinated Materials (NFMLab), Department of Chemistry, Materials, and Chemical Engineering “Giulio Natta”, Politecnico di Milano, Via L. Mancinelli 7, 20131 Milan, Italy
E-mail: pierangelo.metrangolo@polimi.it, giuseppe.resnati@polimi.it
Fax: +39 02 2399 3080
Tel: +39 02 2399 3041 (PM)

b Department of Chemistry and NIS, University of Turin, via P. Giuria 7, 10125 Turin, Italy

c VTT-Technical Research Centre of Finland, Biologinkuja 7, 02150 Espoo, Finland

Abstract

Six halogen-bonded cocrystals involving aromatic donors have been studied by far-IR spectroscopy. Characteristic redshift and intensity enhancement of the C–I stretching band have been observed, which provided a distinct signature of the halogen bond involving iodopentafluorobenzene.

Graphical abstract: Characteristic redshift and intensity enhancement as far-IR fingerprints of the halogen bond involving aromatic donors

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Article information

DOI
https://doi.org/10.1039/C5CE02385H
Article type
Communication
Submitted
05 Dec 2015
Accepted
12 Jan 2016
First published
21 Jan 2016

CrystEngComm, 2016,18, 2247-2250

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Characteristic redshift and intensity enhancement as far-IR fingerprints of the halogen bond involving aromatic donors

V. Vasylyeva, L. Catalano, C. Nervi, R. Gobetto, P. Metrangolo and G. Resnati, CrystEngComm, 2016, 18, 2247 DOI: 10.1039/C5CE02385H

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