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Issue 4, 2017
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Degradable fluorescent single-chain nanoparticles based on metathesis polymers

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Abstract

We introduce the facile synthesis of fluorescent single-chain nanoparticles (SCNPs) based on chain-shattering acyclic diene metathesis (ADMET) polymers featuring self-immolative azobenzene motifs. An electrophilic alkoxyetherification is utilized to introduce the photoreactive moieties required for the subsequent chain collapse via UV-induced nitrile imine-mediated tetrazole–ene cycloaddition (NITEC).

Graphical abstract: Degradable fluorescent single-chain nanoparticles based on metathesis polymers

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Article information


Submitted
24 Oct 2016
Accepted
12 Dec 2016
First published
14 Dec 2016

Chem. Commun., 2017,53, 775-778
Article type
Communication

Degradable fluorescent single-chain nanoparticles based on metathesis polymers

J. T. Offenloch, J. Willenbacher, P. Tzvetkova, C. Heiler, H. Mutlu and C. Barner-Kowollik, Chem. Commun., 2017, 53, 775
DOI: 10.1039/C6CC08554G

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