Issue 100, 2016
From the journal:

Chemical Communications

Diastereoselective construction of cyclopent-2-enone-4-ols from aldehydes and 1,2-allenones catalyzed by N-heterocyclic carbene†

Dengke Ma,a   Chunling Fua  and  Shengming Ma*a  

* Corresponding authors

a Laboratory of Molecular Recognition and Synthesis, Department of Chemistry, Zhejiang University, Hangzhou 310027, Zhejiang, People's Republic of China
E-mail: masm@sioc.ac.cn

Abstract

Cyclopent-2-enone-4-ols have been prepared highly diastereoselectively from readily available aromatic aldehydes and 1,2-allenones catalyzed by N-heterocyclic carbene. Mechanistic studies showed that there are four possible pathways.

Graphical abstract: Diastereoselective construction of cyclopent-2-enone-4-ols from aldehydes and 1,2-allenones catalyzed by N-heterocyclic carbene

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C6CC07974A
Article type
Communication
Submitted
02 Oct 2016
Accepted
21 Nov 2016
First published
22 Nov 2016

Chem. Commun., 2016,52, 14426-14429

Permissions

Request permissions

Diastereoselective construction of cyclopent-2-enone-4-ols from aldehydes and 1,2-allenones catalyzed by N-heterocyclic carbene

D. Ma, C. Fu and S. Ma, Chem. Commun., 2016, 52, 14426 DOI: 10.1039/C6CC07974A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements