An air-stable mononuclear Co(II) complex bearing an o-carborane dithiolate ligand has been synthesized which shows slow relaxation of magnetization in the absence of an applied field and a hysteresis loop at 1.8 K. This is the first example of a carborane-incorporated complex that displays SMM properties.
D. Tu, D. Shao, H. Yan and C. Lu, Chem. Commun., 2016, 52, 14326 DOI: 10.1039/C6CC07728E
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