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Issue 88, 2016

Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor

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Abstract

Room-temperature accelerated aging in the solid state has been applied for atom- and energy-efficient activation of either one or two C–H bonds of azobenzene and methyl orange by palladium(II) acetate. Organopalladium complexes are prepared in quantitative reactions without potentially harmful side products. Dicyclopalladated methyl orange is water-soluble and is a selective chromogenic biothiol sensor at physiologically-relevant micromolar concentrations in buffered aqueous media.

Graphical abstract: Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor

Supplementary files

Article information


Submitted
22 Jul 2016
Accepted
01 Sep 2016
First published
01 Sep 2016

Chem. Commun., 2016,52, 12960-12963
Article type
Communication

Vapour-induced solid-state C–H bond activation for the clean synthesis of an organopalladium biothiol sensor

A. Monas, K. Užarević, I. Halasz, M. J. Kulcsár and M. Ćurić, Chem. Commun., 2016, 52, 12960 DOI: 10.1039/C6CC06062E

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