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Issue 67, 2016
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Facile and efficient formation and dissociation of a pseudo[2]rotaxane by a slippage approach using pillar[5]arene-based cyclic host liquid and solvent

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Abstract

A pillar[5]arene-based pseudo[2]rotaxane was synthesized using a slippage method by only heating an axle with bulky valine derivative ends in a cyclic host liquid (CHL), which is liquid at room temperature. The pseudo[2]rotaxane synthesized in a CHL can be converted back to the starting components, i.e., the pillar[5]arene wheel and the axle, by heating in a solvent.

Graphical abstract: Facile and efficient formation and dissociation of a pseudo[2]rotaxane by a slippage approach using pillar[5]arene-based cyclic host liquid and solvent

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Publication details

The article was received on 04 Jul 2016, accepted on 20 Jul 2016 and first published on 21 Jul 2016


Article type: Communication
DOI: 10.1039/C6CC05514A
Chem. Commun., 2016,52, 10297-10300

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    Facile and efficient formation and dissociation of a pseudo[2]rotaxane by a slippage approach using pillar[5]arene-based cyclic host liquid and solvent

    T. Ogoshi, Y. Tamura, D. Yamafuji, T. Aoki and T. Yamagishi, Chem. Commun., 2016, 52, 10297
    DOI: 10.1039/C6CC05514A

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