A planar triangular Dy3 + Dy3 single-molecule magnet with a toroidal magnetic moment

Xiao-Lei Li; Jianfeng Wu; Jinkui Tang; Boris Le Guennic; Wei Shi; Peng Cheng

doi:10.1039/C6CC05326B

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A planar triangular Dy₃ + Dy₃ single-molecule magnet with a toroidal magnetic moment†

Xiao-Lei Li,^ab Jianfeng Wu,^a Jinkui Tang,*^a Boris Le Guennic,*^c Wei Shi*^b and Peng Cheng^b

Author affiliations

* Corresponding authors

^a State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China
E-mail: tang@ciac.ac.cn
Fax: +86 431 85262878

^b Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (MOE), and Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, P. R. China

^c Institut des Sciences Chimiques de Rennes, UMR 6226 CNRS-Université de Rennes 1, 263 Avenue du General Leclerc, 35042 Rennes Cedex, France

Abstract

A unique Dy₆ complex with a planar Dy₃ + Dy₃ structure was assembled by delicately modifying the axial ligands. Single-molecule magnet behavior and meanwhile a toroidal magnetic moment in the ground state have been observed.

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Article information

DOI: https://doi.org/10.1039/C6CC05326B
Article type: Communication
Submitted: 27 Jun 2016
Accepted: 29 Jun 2016
First published: 30 Jun 2016

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Chem. Commun., 2016,52, 9570-9573

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A planar triangular Dy₃ + Dy₃ single-molecule magnet with a toroidal magnetic moment

X. Li, J. Wu, J. Tang, B. Le Guennic, W. Shi and P. Cheng, Chem. Commun., 2016, 52, 9570 DOI: 10.1039/C6CC05326B

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