A new method was developed to synthesize iodine-substituted Z-enamides through N-iodosuccinimide-mediated intermolecular iodofunctionalization of allenamides with indoles, pyrroles, and furans. These reactions proceed rapidly and tolerate a broad scope of substrates. The conjugated sulfimide ion species probably acts as the key intermediate.
H. Li, X. Li, Z. Zhao, T. Ma, C. Sun and B. Yang, Chem. Commun., 2016, 52, 10167 DOI: 10.1039/C6CC05046H
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