From discrete molecule, to polymer, to MOF: mapping the coordination chemistry of CdII using 113Cd solid-state NMR

Jamie M. Frost; Libor Kobera; Amélie Pialat; Yixin Zhang; Scott A. Southern; Bulat Gabidullin; David L. Bryce; Muralee Murugesu

doi:10.1039/C6CC04940K

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From discrete molecule, to polymer, to MOF: mapping the coordination chemistry of Cd^II using ¹¹³Cd solid-state NMR†

Jamie M. Frost,

^a Libor Kobera,^a Amélie Pialat,^a Yixin Zhang,^a Scott A. Southern,^a Bulat Gabidullin,^a David L. Bryce*^a and Muralee Murugesu

*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry and Biomolecular Sciences, University of Ottawa, 10 Marie Curie, Ottawa, ON, Canada K1N 6N5
E-mail: m.murugesu@uottawa.ca, David.Bryce@uottawa.ca
Fax: +1 (613) 562 5170
Tel: +1 (613) 562 5800 ext. 2733

Abstract

Studies of three related Cd^II systems (a discrete [Cd^II₂] unit, a one-dimensional [Cd^II₂]_n coordination polymer and a Cd^II-based MOF) all derived from the ligand 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine, reveal an exceptionally rare example of ¹¹³Cd–¹¹³Cd J coupling in the polymer that is detectable by solid-state NMR (²J_Cd–Cd = ∼65 Hz).

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Article information

DOI: https://doi.org/10.1039/C6CC04940K
Article type: Communication
Submitted: 14 Jun 2016
Accepted: 02 Aug 2016
First published: 02 Aug 2016

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Chem. Commun., 2016,52, 10680-10683

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From discrete molecule, to polymer, to MOF: mapping the coordination chemistry of Cd^II using ¹¹³Cd solid-state NMR

J. M. Frost, L. Kobera, A. Pialat, Y. Zhang, S. A. Southern, B. Gabidullin, D. L. Bryce and M. Murugesu, Chem. Commun., 2016, 52, 10680 DOI: 10.1039/C6CC04940K

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