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Abstract | Cited by

Enantioselective total synthesis of (+)-Lingzhiol has been achieved. It is the first example of in tandem semipinacol rearrangement reactions, the migrated aryl group further reacting with the carbonyl oxonium electrophile to furnish a polycyclic skeleton. Our synthesis involves 13 steps and proceeds in 6% overall yield.

Graphical abstract: Enantioselective total synthesis of (+)-Lingzhiol via tandem semipinacol rearrangement/Friedel–Crafts type cyclization

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