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Issue 62, 2016
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Enantioselective sulfoxidation reaction catalyzed by a G-quadruplex DNA metalloenzyme

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Abstract

Enantioselective sulfoxidation reaction is achieved for the first time by a DNA metalloenzyme assembled with the human telomeric G-quadruplex DNA and Cu(II)–4,4′-bimethyl-2,2′-bipyridine complex, and the mixed G-quadruplex architectures are responsible for the catalytic enantioselectivity and activity.

Graphical abstract: Enantioselective sulfoxidation reaction catalyzed by a G-quadruplex DNA metalloenzyme

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Article information


Submitted
11 Apr 2016
Accepted
23 Jun 2016
First published
23 Jun 2016

Chem. Commun., 2016,52, 9644-9647
Article type
Communication

Enantioselective sulfoxidation reaction catalyzed by a G-quadruplex DNA metalloenzyme

M. Cheng, Y. Li, J. Zhou, G. Jia, S. Lu, Y. Yang and C. Li, Chem. Commun., 2016, 52, 9644
DOI: 10.1039/C6CC03016E

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