Issue 56, 2016
From the journal:

Chemical Communications

Crystal engineering to control the magnetic interaction between weak ferromagnetic single-chain magnets assembled in a 3D framework†

Lei Su,a   Wei-Chao Song,b   Jiong-Peng Zhao*a  and  Fu-Chen Liu*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, TKL of Organic Solar Cells and Photochemical Conversion, Tianjin University of Technology, Tianjin 300384, China
E-mail: horryzhao@yahoo.com, fuchenliutj@yahoo.com

b TKL of Structure and Performance for Functional Molecules, College of Chemistry, Tianjin Normal University, Tianjin 300387, P. R. China

Abstract

A new single-chain-magnet (SCM), [Co4(OMe)3(HCO2)2(L)3·DMF]n, (L = 4-(pyridin-4-yl)benzolate) (2), was constructed by changing the spacers of a weak ferromagnetic single-chain magnet [Co8(OMe)6(HCO2)4(isonic)6·H2O]n (1). By contrasting the magnetism of the two complexes, it is found that the longer the linker the stronger the magnetic properties.

Graphical abstract: Crystal engineering to control the magnetic interaction between weak ferromagnetic single-chain magnets assembled in a 3D framework

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Article information

DOI
https://doi.org/10.1039/C6CC02702D
Article type
Communication
Submitted
31 Mar 2016
Accepted
12 Jun 2016
First published
13 Jun 2016

Chem. Commun., 2016,52, 8722-8725

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Crystal engineering to control the magnetic interaction between weak ferromagnetic single-chain magnets assembled in a 3D framework

L. Su, W. Song, J. Zhao and F. Liu, Chem. Commun., 2016, 52, 8722 DOI: 10.1039/C6CC02702D

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