A single-stranded {Gd18} nanowheel with a symmetric polydentate diacylhydrazone ligand

Kai Wang; Zi-Lu Chen; Hua-Hong Zou; Kun Hu; Hai-Ye Li; Zhong Zhang; Wei-Yin Sun; Fu-Pei Liang

doi:10.1039/C6CC02208A

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A single-stranded {Gd₁₈} nanowheel with a symmetric polydentate diacylhydrazone ligand†

Kai Wang,^a Zi-Lu Chen,^b Hua-Hong Zou,^b Kun Hu,^b Hai-Ye Li,^b Zhong Zhang,^b Wei-Yin Sun^c and Fu-Pei Liang*^ab

Author affiliations

* Corresponding authors

^a Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, China
E-mail: fliangoffice@yahoo.com

^b State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmacy, Guangxi Normal University, Guilin, China

^c Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing, China

Abstract

An unprecedented {Gd₁₈} nanowheel was solvothermally synthesized with a novel diacylhydrazone ligand. It features a rare single-stranded skeleton just like a Reuleaux triangle with vertices buckled in, represents the highest nuclearity and largest size in lanthanide (Ln) wheels reported so far, and shows a large magnetocaloric effect (MCE).

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Article information

DOI: https://doi.org/10.1039/C6CC02208A
Article type: Communication
Submitted: 13 Mar 2016
Accepted: 02 Jun 2016
First published: 02 Jun 2016

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Chem. Commun., 2016,52, 8297-8300

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A single-stranded {Gd₁₈} nanowheel with a symmetric polydentate diacylhydrazone ligand

K. Wang, Z. Chen, H. Zou, K. Hu, H. Li, Z. Zhang, W. Sun and F. Liang, Chem. Commun., 2016, 52, 8297 DOI: 10.1039/C6CC02208A

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Chemical Communications