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Issue 38, 2016
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Synchronous intramolecular cycloadditions of the polyene macrolactam polyketide heronamide C

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Abstract

A growing number of natural products appear to arise from biosynthetic pathways that involve pericyclic reactions. We show here that for the heronamides this can occur via two spontaneous pathways involving alternative thermal or photochemical intramolecular cycloadditions.

Graphical abstract: Synchronous intramolecular cycloadditions of the polyene macrolactam polyketide heronamide C

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Supplementary files

Article information


Submitted
03 Mar 2016
Accepted
31 Mar 2016
First published
31 Mar 2016

This article is Open Access

Chem. Commun., 2016,52, 6383-6386
Article type
Communication

Synchronous intramolecular cycloadditions of the polyene macrolactam polyketide heronamide C

T. J. Booth, S. Alt, R. J. Capon and B. Wilkinson, Chem. Commun., 2016, 52, 6383
DOI: 10.1039/C6CC01930G

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