Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 27th March 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 31, 2016
Previous Article Next Article

Ferromagnetic ordering of –[Sm(III)-radical]n– coordination polymers

Author affiliations

Abstract

[Sm(hfac)3(boaDTDA)]n is the first coordination compound of a thiazyl-based neutral radical ligand to exhibit ferromagnetic ordering; TC = 3 K. The [Sm(III)-radical]n species is soluble in common organic solvents and can be sublimed quantitatively. A McConnell I mechanism is implicated in local exchange pathways that contribute to cooperative magnetic properties.

Graphical abstract: Ferromagnetic ordering of –[Sm(iii)-radical]n– coordination polymers

Back to tab navigation

Supplementary files

Publication details

The article was received on 19 Feb 2016, accepted on 14 Mar 2016 and first published on 14 Mar 2016


Article type: Communication
DOI: 10.1039/C6CC01548D
Author version
available:
Download author version (PDF)
Citation: Chem. Commun., 2016,52, 5414-5417

  •   Request permissions

    Ferromagnetic ordering of –[Sm(III)-radical]n– coordination polymers

    E. M. Fatila, A. C. Maahs, M. B. Mills, M. Rouzières, D. V. Soldatov, R. Clérac and K. E. Preuss, Chem. Commun., 2016, 52, 5414
    DOI: 10.1039/C6CC01548D

Search articles by author

Spotlight

Advertisements