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Issue 31, 2016
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Ferromagnetic ordering of –[Sm(iii)-radical]n– coordination polymers

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Abstract

[Sm(hfac)3(boaDTDA)]n is the first coordination compound of a thiazyl-based neutral radical ligand to exhibit ferromagnetic ordering; TC = 3 K. The [Sm(III)-radical]n species is soluble in common organic solvents and can be sublimed quantitatively. A McConnell I mechanism is implicated in local exchange pathways that contribute to cooperative magnetic properties.

Graphical abstract: Ferromagnetic ordering of –[Sm(iii)-radical]n– coordination polymers

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Supplementary files

Article information


Submitted
19 Feb 2016
Accepted
14 Mar 2016
First published
14 Mar 2016

Chem. Commun., 2016,52, 5414-5417
Article type
Communication
Author version available

Ferromagnetic ordering of –[Sm(III)-radical]n– coordination polymers

E. M. Fatila, A. C. Maahs, M. B. Mills, M. Rouzières, D. V. Soldatov, R. Clérac and K. E. Preuss, Chem. Commun., 2016, 52, 5414
DOI: 10.1039/C6CC01548D

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