Issue 37, 2016
From the journal:

Chemical Communications

Evidence for an intrinsic binding force between dodecaborate dianions and receptors with hydrophobic binding pockets†

Jonas Warneke,*a   Carsten Jenne,b   Johannes Bernarding,c   Vladimir A. Azov*a  and  Markus Plaumann*c  

* Corresponding authors

a Universität Bremen, Institut für Angewandte und Physikalische Chemie, Leobener Str. NW 2, D-28334 Bremen, Germany
E-mail: jonas.warneke@uni-bremen.de, vazov@uni-bremen.de

b Bergische Universität Wuppertal, Fakultät für Mathematik und Naturwissenschaften, Gaussstrasse 20, D-42119 Wuppertal, Germany

c Otto-von-Guericke Universität Magdeburg, Institut für Biometrie und Medizinische Informatik, Leipziger Str. 44, D-39120 Magdeburg, Germany
E-mail: markus.plaumann@med.ovgu.de

Abstract

A gas phase binding study revealed strong intrinsic intermolecular interactions between dianionic halogenated closo-dodecaborates [B12X12]2− and several neutral organic receptors. Oxidation of a tetrathiafulvalene host allowed switching between two host–guest binding modes in a supramolecular complex. Complexes of β-cyclodextrin with [B12F12]2− show remarkable stability in the gas phase and were successfully tested as carriers for the delivery of boron clusters into cancer cells.

Graphical abstract: Evidence for an intrinsic binding force between dodecaborate dianions and receptors with hydrophobic binding pockets

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Article information

DOI
https://doi.org/10.1039/C6CC01233G
Article type
Communication
Submitted
08 Feb 2016
Accepted
01 Apr 2016
First published
04 Apr 2016
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2016,52, 6300-6303

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Evidence for an intrinsic binding force between dodecaborate dianions and receptors with hydrophobic binding pockets

J. Warneke, C. Jenne, J. Bernarding, V. A. Azov and M. Plaumann, Chem. Commun., 2016, 52, 6300 DOI: 10.1039/C6CC01233G

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