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Issue 32, 2016
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1,7-Naphthodiyne: a new platform for the synthesis of novel, sterically congested PAHs

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Abstract

The synthesis of an efficient precursor of the novel 1,7-naphthodiyne synthon is reported. Preliminary experiments demonstrate the usefulness of this platform for the synthesis of sterically congested polyarenes, such as helicenes and angularly fused acene derivatives. Furthermore, a novel intramolecular aryne trapping reaction is described.

Graphical abstract: 1,7-Naphthodiyne: a new platform for the synthesis of novel, sterically congested PAHs

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The article was received on 06 Feb 2016, accepted on 15 Mar 2016 and first published on 17 Mar 2016


Article type: Communication
DOI: 10.1039/C6CC01214K
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Citation: Chem. Commun., 2016,52, 5534-5537
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    1,7-Naphthodiyne: a new platform for the synthesis of novel, sterically congested PAHs

    I. Pozo, A. Cobas, D. Peña, E. Guitián and D. Pérez, Chem. Commun., 2016, 52, 5534
    DOI: 10.1039/C6CC01214K

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