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Issue 33, 2016
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Multifunctionalization of C70 at the two polar regions with a high regioselectivity via oxazolination and benzylation reactions

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Abstract

C70 multiadducts with a novel 1,2,3,4,41,56,57,58-configuration were prepared via oxazolination and benzylation reactions. The structures of the adducts were determined by single crystal X-ray diffraction and spectral characterization. The compounds exhibit a high LUMO level, and result in a high open-circuit voltage in devices with P3HT.

Graphical abstract: Multifunctionalization of C70 at the two polar regions with a high regioselectivity via oxazolination and benzylation reactions

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Article information


Submitted
01 Feb 2016
Accepted
18 Mar 2016
First published
18 Mar 2016

Chem. Commun., 2016,52, 5710-5713
Article type
Communication

Multifunctionalization of C70 at the two polar regions with a high regioselectivity via oxazolination and benzylation reactions

S. Li, Z. Li, T. Nakagawa, I. Jeon, Z. Ju, Y. Matsuo and X. Gao, Chem. Commun., 2016, 52, 5710
DOI: 10.1039/C6CC00997B

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