Issue 34, 2016

Efficient multi-click approach to well-defined two-faced octasilsesquioxanes: the first perfect Janus nanocube

Abstract

The preparation of the first structurally well-defined Janus nanocube showing two chemically distinct opposed faces is described. The synthetic approach is based on a highly efficient and symmetry-controlled CuAAC functionalization of an octa-azido cubic silsesquioxane with a conformationally constrained tetra-alkyne with an appropriate spatial orientation of the triple bonds.

Graphical abstract: Efficient multi-click approach to well-defined two-faced octasilsesquioxanes: the first perfect Janus nanocube

Supplementary files

Article information

Article type
Communication
Submitted
28 Jan 2016
Accepted
01 Mar 2016
First published
01 Mar 2016
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2016,52, 5792-5795

Author version available

Efficient multi-click approach to well-defined two-faced octasilsesquioxanes: the first perfect Janus nanocube

A. Blázquez-Moraleja, M. Eugenia Pérez-Ojeda, J. R. Suárez, M. Luisa Jimeno and J. L. Chiara, Chem. Commun., 2016, 52, 5792 DOI: 10.1039/C6CC00896H

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