Issue 32, 2016

Palladium-catalyzed silylation reaction between benzylic halides and silylboronate

Abstract

An efficient Pd-catalyzed silylation reaction of benzylic halides with silylboronate is reported. In this reaction, primary and secondary benzylic halides could react well with silylboronates to afford benzylic silanes. This reaction accommodates a broad substrate scope and proceeds smoothly under very mild reaction conditions. The corresponding products could be obtained in moderate to high yields and with stereospecificity.

Graphical abstract: Palladium-catalyzed silylation reaction between benzylic halides and silylboronate

Supplementary files

Article information

Article type
Communication
Submitted
25 Jan 2016
Accepted
21 Mar 2016
First published
21 Mar 2016

Chem. Commun., 2016,52, 5609-5612

Palladium-catalyzed silylation reaction between benzylic halides and silylboronate

Z. Huang, R. Ding, P. Wang, Y. Xu and T. Loh, Chem. Commun., 2016, 52, 5609 DOI: 10.1039/C6CC00713A

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