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Issue 28, 2016

Synthesis of quaternary aryl phosphonium salts: photoredox-mediated phosphine arylation

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Abstract

We report a synthesis method for the construction of quaternary aryl phoshonium salts at ambient temperature. The regiospecific reaction involves the coupling of phosphines with aryl radicals derived from diaryliodonium salts under photoredox conditions.

Graphical abstract: Synthesis of quaternary aryl phosphonium salts: photoredox-mediated phosphine arylation

Supplementary files

Article information


Submitted
20 Jan 2016
Accepted
10 Feb 2016
First published
12 Feb 2016

Chem. Commun., 2016,52, 4987-4990
Article type
Communication

Synthesis of quaternary aryl phosphonium salts: photoredox-mediated phosphine arylation

A. F. Fearnley, J. An, M. Jackson, P. Lindovska and R. M. Denton, Chem. Commun., 2016, 52, 4987 DOI: 10.1039/C6CC00556J

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