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Issue 19, 2016
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The transformation of polyoxometalates in the formation of intercluster compound [Ag41(α-SiW10O37)(tBuC[triple bond, length as m-dash]C)27(CH3CN)3][β-SiW12O40]

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Abstract

We report a unique intercluster compound comprising a Ag41 cage encapsulating a divacant [α-SiW10O37]10− anion and a complete [β-SiW12O40]4− anion as a counteranion. Two electro-redox centers associated with the inner and outer POM anions show interesting electrochemical behaviours, because the stable Ag41 cage acts as an electron transfer mediator.

Graphical abstract: The transformation of polyoxometalates in the formation of intercluster compound [Ag41(α-SiW10O37)(tBuC [[triple bond, length as m-dash]] C)27(CH3CN)3][β-SiW12O40]

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Publication details

The article was received on 19 Jan 2016, accepted on 28 Jan 2016 and first published on 28 Jan 2016


Article type: Communication
DOI: 10.1039/C6CC00524A
Chem. Commun., 2016,52, 3801-3804

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    The transformation of polyoxometalates in the formation of intercluster compound [Ag41(α-SiW10O37)(tBuC[triple bond, length as m-dash]C)27(CH3CN)3][β-SiW12O40]

    K. Liu, X. Liu, Z. Guan, K. Shi, Y. Lin and Q. Wang, Chem. Commun., 2016, 52, 3801
    DOI: 10.1039/C6CC00524A

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