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Abstract | Cited by

A novel 3D MOF based on dysprosium(III) oxalate and 1,10-phenanthroline (phen), {[Dy(C2O4)1.5phen]·0.5H2O}n (1), has been hydrothermally synthesized. The Dy3+ ion acts as a typical Y-shaped node, linking to each other to generate an interesting 3D topology structure. Complex 1 is the first 3D DyMOF displaying both ferromagnetic coupling and field-induced two-step magnetic relaxation.

Graphical abstract: A 3D MOF constructed from dysprosium(iii) oxalate and capping ligands: ferromagnetic coupling and field-induced two-step magnetic relaxation

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