A coordination polymer is shown to possess anomalous anisotropic thermal expansion. Guest water molecules present in the as-synthesised material can be removed upon activation without loss of crystal singularity. The fully dehydrated form shows considerably different thermal expansion behaviour as compared to the hydrate.
P. Lama, L. O. Alimi, R. K. Das and L. J. Barbour, Chem. Commun., 2016, 52, 3231 DOI: 10.1039/C6CC00158K
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