Issue 12, 2016

A triple-function nanotube as a reactant reservoir, reaction platform, and byproduct scavenger for photo-cyclopropanation

Abstract

Herein, we report the advanced-concept triple-functionality of a metal–organic nanotube (MONT), which acts as a reservoir for unstable reactants, a photoreaction platform, and a scavenger for byproduct iodine. Self-assembly of CdI2 with a new Y-type ligand (L) produces the substantial 1D MOF, [CdI2(L)], thus forming a thick nanotube with a 1.4 nm diameter.

Graphical abstract: A triple-function nanotube as a reactant reservoir, reaction platform, and byproduct scavenger for photo-cyclopropanation

Supplementary files

Article information

Article type
Communication
Submitted
03 Dec 2015
Accepted
23 Dec 2015
First published
23 Dec 2015

Chem. Commun., 2016,52, 2545-2548

A triple-function nanotube as a reactant reservoir, reaction platform, and byproduct scavenger for photo-cyclopropanation

J. G. Kim, T. H. Noh, Y. Cho, J. K. Park and O. Jung, Chem. Commun., 2016, 52, 2545 DOI: 10.1039/C5CC09967F

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