Single crystal to single crystal [2+2] photoreactions in chloride and sulphate salts of 4-amino-cinnamic acid via solid-solution formation: a structural and kinetic study

Abstract

A set of molecular salts with general formula [1H]_nA·xH₂O (1 = 4-amino-cinnamic acid, Aⁿ⁻ = NO₃⁻, BF₄⁻, PF₆⁻, SO₄²⁻, x = 0, 1) was prepared and structurally characterized. [1H]Cl and [1H]₂SO₄·H₂O(II) were found to undergo an SCSC stepwise [2+2] photodimerization, which was followed by X-ray diffraction; a kinetic analysis was performed on single crystals of both salts. In the case of [1H]Cl the photoreaction was also studied on polycrystalline materials.