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Issue 32, 2016
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Double hydrophosphination of alkynes promoted by rhodium: the key role of an N-heterocyclic carbene ligand

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Abstract

The regioselective double hydrophosphination of alkynes mediated by rhodium catalysts is presented. The distinctive stereoelectronic properties of the NHC ligand prevent the catalyst deactivation by diphosphine coordination thereby allowing for the closing of a productive catalytic cycle.

Graphical abstract: Double hydrophosphination of alkynes promoted by rhodium: the key role of an N-heterocyclic carbene ligand

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Publication details

The article was received on 04 Nov 2015, accepted on 17 Mar 2016 and first published on 17 Mar 2016


Article type: Communication
DOI: 10.1039/C5CC09156J
Citation: Chem. Commun., 2016,52, 5554-5557

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    Double hydrophosphination of alkynes promoted by rhodium: the key role of an N-heterocyclic carbene ligand

    A. Di Giuseppe, R. De Luca, R. Castarlenas, J. J. Pérez-Torrente, M. Crucianelli and L. A. Oro, Chem. Commun., 2016, 52, 5554
    DOI: 10.1039/C5CC09156J

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