Rhodium-catalyzed tunable oxidative cyclization toward the selective synthesis of α-pyrones and furans

Jiaping Wu; Dongxu Wang; Yanjun Wan; Cheng Ma

doi:10.1039/C5CC09137C

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Rhodium-catalyzed tunable oxidative cyclization toward the selective synthesis of α-pyrones and furans†

Jiaping Wu,^a Dongxu Wang,^a Yanjun Wan^a and Cheng Ma*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Zhejiang University, 20 Yugu Road, Hangzhou 310027, China
E-mail: mcorg@zju.edu.cn

Abstract

The rhodium(III)-catalyzed tunable oxidative cyclization of readily available N-tosylacrylamides and diazo compounds is presented, which offers a novel method for the selective construction of fully substituted α-pyrones and furans in a regiospecific manner by employing the acylsulfonamide group as a versatile in situ removable directing group.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C5CC09137C
Article type: Communication
Submitted: 04 Nov 2015
Accepted: 01 Dec 2015
First published: 01 Dec 2015

Download Citation

Chem. Commun., 2016,52, 1661-1664

Permissions

Request permissions

Rhodium-catalyzed tunable oxidative cyclization toward the selective synthesis of α-pyrones and furans

J. Wu, D. Wang, Y. Wan and C. Ma, Chem. Commun., 2016, 52, 1661 DOI: 10.1039/C5CC09137C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications

Rhodium-catalyzed tunable oxidative cyclization toward the selective synthesis of α-pyrones and furans†

Abstract

Supplementary files

Article information

Download Citation

Permissions

Rhodium-catalyzed tunable oxidative cyclization toward the selective synthesis of α-pyrones and furans

Social activity

Search articles by author

Spotlight

Advertisements