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FTIR spectra of 12CO2 and 12CO2 + 13CO2 mixtures adsorbed on MIL-53(Al) reveal the formation of highly symmetric dimeric (CO2)2 species connected to two structural OH groups.

Graphical abstract: Adsorption of CO2 on MIL-53(Al): FTIR evidence of the formation of dimeric CO2 species

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