Herein, we report the first example where an M-enantiomer of a chiral metal complex can selectively stabilize a left-handed G-quadruplex, but its P-enantiomer cannot. The interactions between the chiral metal complexes and the left-handed G-quadruplex were evaluated by UV melting, circular dichroism, isothermal titration calorimetry, gel electrophoresis and NMR titrations.
A. Zhao, C. Zhao, J. Ren and X. Qu, Chem. Commun., 2016, 52, 1365 DOI: 10.1039/C5CC08401F
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