The total synthesis and stereochemical assignment of scytonemin A†
Abstract
The total synthesis of scytonemin A and its C-9 epimer, as well as elucidation of the absolute stereochemistry of natural scytonemin A is described.
* Corresponding authors
a
Laboratory of Chemical Genomics, Peking University Shenzhen Graduate School, University Town, Xili, Shenzhen, China
E-mail:
yet@pkusz.edu.cn, xuzs@pkusz.edu.cn
b Department of Applied Biology & Chemical Technology, The Hong Kong Polytechnic University, Hong Kong, China
The total synthesis of scytonemin A and its C-9 epimer, as well as elucidation of the absolute stereochemistry of natural scytonemin A is described.
J. Liu, L. Wang, J. Zhang, Z. Xu and T. Ye, Chem. Commun., 2016, 52, 1002 DOI: 10.1039/C5CC08324A
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