The Z and E isomers of the iodinated TTF derivative (Z,E)-Me2I2-TTF co-crystallize in a mixed-valence salt with Br− anions, and are segregated into Z and E stacks, each of them with a different charge localization pattern, which also revealed charge-assisted halogen bonding.
![Graphical abstract: Correlating conduction properties with the molecular symmetry: segregation of Z and E isomers in the charge-assisted, halogen-bonded cocrystal [(Z,E)-Me2I2TTF]2Br](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C5CC08176A&imageInfo.ImageIdentifier.Year=2016)
O. Jeannin, E. Canadell, P. Auban-Senzier and M. Fourmigué, Chem. Commun., 2016, 52, 308 DOI: 10.1039/C5CC08176A
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...
