The synthesis of the first example of a third-row metallocorrolazine characterized by single crystal X-ray diffraction is reported. This ReV(O) porphyrinoid complex shows an exclusively ligand-based reactivity with strong acids and oxidizing agents. The one-electron oxidized π-radical-cation complex is capable of H-atom abstraction.
J. P. T. Zaragoza, M. A. Siegler and D. P. Goldberg, Chem. Commun., 2016, 52, 167 DOI: 10.1039/C5CC07956J
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