Issue 7, 2016
From the journal:

Chemical Communications

Cobalt(i)-catalysed CH-alkylation of terminal olefins, and beyond†

Maciej Giedyk,a   Katarzyna Goliszewska,a   Keith ó Proinsiasa  and  Dorota Gryko*a  

* Corresponding authors

a Institute of Organic Chemistry Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland
E-mail: dorota.gryko@icho.edu.pl
Web: http://ww2.icho.edu.pl/gryko_group

Abstract

Cobalester, a natural nontoxic vitamin B12 derivative, was found to catalyse unusual olefinic sp2 C–H alkylation with diazo reagents as a carbene source instead of the expected cyclopropanation.

Graphical abstract: Cobalt(i)-catalysed CH-alkylation of terminal olefins, and beyond

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Article information

DOI
https://doi.org/10.1039/C5CC07363D
Article type
Communication
Submitted
02 Sep 2015
Accepted
11 Nov 2015
First published
12 Nov 2015

Chem. Commun., 2016,52, 1389-1392

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Cobalt(I)-catalysed CH-alkylation of terminal olefins, and beyond

M. Giedyk, K. Goliszewska, K. ó Proinsias and D. Gryko, Chem. Commun., 2016, 52, 1389 DOI: 10.1039/C5CC07363D

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