Issue 22, 2015

Enhancing device efficiencies of solid-state white light-emitting electrochemical cells by employing waveguide coupling

Abstract

Solid-state white light-emitting electrochemical cells (LECs) have received intense scientific attention owing to their potential applications in display and lighting. Although device efficiencies of white LECs have been significantly improved in recent years, further improvements are still required for their practical applications. In this work, we demonstrate the enhancement of device efficiencies of white LECs by employing waveguide coupling. Two transparent photoresist (TPR) layers doped with TiO2 nanoparticles (NPs) are inserted between the indium tin oxide (ITO) layer and the glass substrate. By tuning the doping concentration of 25 nm TiO2 NPs in the upper TPR layer to adjust the refractive index, effective waveguide coupling between the ITO layer and the lower TPR layer can be achieved. Since the lower TPR layer contains 250 nm TiO2 NPs, electroluminescence (EL) outcoupled from the ITO layer can be scattered and redirected into the forward direction. Furthermore, the EL trapped in the glass substrate can also transmit into the lower TPR layer and then is scattered to the forward direction. When the EL trapped in the ITO layer and the glass substrate can be effectively recycled into the forward direction, the peak external quantum efficiency and power efficiency obtained in white LECs employing waveguide coupling are up to 19.4% and 34.1 lm W−1, respectively. These efficiencies are among the highest reported for white LECs and thus confirm that waveguide coupling would be useful for realizing highly efficient white LECs. In addition to the enhanced device efficiencies, improved color migration of EL spectra, which is desired for lighting applications, can be obtained in white LECs with scattering waveguide layers since EL of different angles can be mixed in the forward direction.

Graphical abstract: Enhancing device efficiencies of solid-state white light-emitting electrochemical cells by employing waveguide coupling

Article information

Article type
Paper
Submitted
19 Mar 2015
Accepted
28 Apr 2015
First published
12 May 2015

J. Mater. Chem. C, 2015,3, 5665-5673

Enhancing device efficiencies of solid-state white light-emitting electrochemical cells by employing waveguide coupling

C. Cheng, C. Wang, J. Cheng, H. Chen, Y. Yeh, H. Su, C. Chang and K. Wong, J. Mater. Chem. C, 2015, 3, 5665 DOI: 10.1039/C5TC00765H

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