Issue 29, 2015

The regulation of hydrophilicity and hydrophobicity of carbon dots via a one-pot approach

Abstract

The regulation of hydrophilicity/hydrophobicity of carbon dots (CDs) at will is most important. One pot simultaneous preparation of hydrophilic and/or hydrophobic CDs is herein reported, via a hydrothermal process with 1-butyl-3-methylimidazolium hexafluorophosphate as the carbon source in a H3PO4–ethanol medium. The hydrophilicity or hydrophobicity of CDs (or their proportions) is simply regulated by varying the H3PO4/ethanol molar ratio. Hydrophilic and hydrophobic CDs are obtained simultaneously with H3PO4/ethanol molar ratios within 0–1.72, while hydrophilic or hydrophobic CDs are the sole product obtained from H3PO4–BmimPF6 or BmimPF6-only systems. The CDs exhibit excitation-dependent maximum fluorescence at 360/440 nm (hydrophilic) and 430/510 nm (hydrophobic), with quantum yields of 17.0% and 7.7%, respectively. Both hydrophilic and hydrophobic CDs obtained by this approach exhibit favorable biocompatibility and offer great potential in bio-imaging as demonstrated for the fluorescent labeling and imaging of live HeLa cells.

Graphical abstract: The regulation of hydrophilicity and hydrophobicity of carbon dots via a one-pot approach

Supplementary files

Article information

Article type
Paper
Submitted
20 May 2015
Accepted
22 Jun 2015
First published
22 Jun 2015

J. Mater. Chem. B, 2015,3, 6013-6018

Author version available

The regulation of hydrophilicity and hydrophobicity of carbon dots via a one-pot approach

Q. Mao, W. Wang, X. Hai, Y. Shu, X. Chen and J. Wang, J. Mater. Chem. B, 2015, 3, 6013 DOI: 10.1039/C5TB00963D

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