A stable inverse opal structure of cadmium chalcogenide for efficient water splitting

Abstract

Cadmium chalcogenide nanocrystals (CCNCs) are regarded as promising materials for photoelectrochemical (PEC) water splitting. However, the relatively low PEC response and poor stability restrict their practical applications. In the present work, we demonstrate that a well-designed inverse opal structure (IOS) composed of CCNCs can achieve an unprecedentedly high photocurrent and hydrogen production rate. In particular, the IOS electrode remains stable during 3 h of continuous illumination, which is even superior to those photoanodes with surface passivation and/or co-catalysts. Quantitative investigation reveals that the IOS possesses high charge-separation efficiency and light-absorption capacity, which eventually result in excellent PEC performance.