Improved rate ability of low cost sulfur cathodes by using ultrathin graphite sheets with self-wrapped function as cheap conductive agent†
Abstract
Rechargeable lithium sulfur batteries are considered as one of the most promising batteries of the future, but they still suffer from poor rate performance due to the insulating nature of sulfur and Li2S, especially in low cost and simple sulfur cathodes. Till date, most of the studies have focused on the design of the state of art S-containing composites or complex electrode architectures. However, few studies have aimed to improve the low cost sulfur cathodes using commercial sulfur powder because of the increased difficulty; moreover, few studies have investigated the effect of conductive agents on the rate ability of lithium sulfur batteries. To improve the rate ability of low cost sulfur cathodes, we propose a cheap conductive agent, namely ultrathin graphite sheet (UGS), prepared by a simple ultrasonic dispersion method to replace commercial carbon blacks. Surprisingly, we find that sulfur particles can be easily wrapped by the small UGS in the electrodes without the assistance of any surfactants or other special methods. This spontaneous wrapping can effectively improve the electrical contact between the micro-sized particles and the UGS. Benefiting from its intrinsic high electronic conductivity and ultrathin sheet structure, a more effective 3D electrical conductive network is formed, which causes the electrode to exhibit lower interphase contact resistance and charge transfer resistance. Thus, the discharge ability and the charge ability of the UGS/sulfur cathode at 1 C or higher rates are much better than that of the nanoscale carbon black/sulfur cathode. Better performance at high rates and a low cost make UGS more suitable for the low cost and high power sulfur cathode.