Issue 3, 2015

Functional superhydrophobic surfaces made of Janus micropillars


We demonstrate the fabrication of superhydrophobic surfaces consisting of micropillars with hydrophobic sidewalls and hydrophilic tops, referred to as Janus micropillars. Therefore we first coat a micropillar array with a mono- or bilayer of polymeric particles, and merge the particles together to shield the top faces while hydrophobizing the walls. After removing the polymer film, the top faces of the micropillar arrays can be selectively chemically functionalised with hydrophilic groups. The Janus arrays remain superhydrophobic even after functionalisation as verified by laser scanning confocal microscopy. The robustness of the superhydrophobic behaviour proves that the stability of the entrapped air cushion is determined by the forces acting at the rim of the micropillars. This insight should stimulate a new way of designing super liquid-repellent surfaces with tunable liquid adhesion. In particular, combining superhydrophobicity with the functionalisation of the top faces of the protrusions with hydrophilic groups may have exciting new applications, including high-density microarrays for high-throughput screening of bioactive molecules, cells, or enzymes or efficient water condensation. However, so far chemical attachment of hydrophilic molecules has been accompanied with complete wetting of the surface underneath. The fabrication of superhydrophobic surfaces where the top faces of the protrusions can be selectively chemically post-functionalised with hydrophilic molecules, while retaining their superhydrophobic properties, is both promising and challenging.

Graphical abstract: Functional superhydrophobic surfaces made of Janus micropillars

Article information

Article type
07 Oct 2014
31 Oct 2014
First published
21 Nov 2014
This article is Open Access
Creative Commons BY license

Soft Matter, 2015,11, 506-515

Author version available

Functional superhydrophobic surfaces made of Janus micropillars

L. Mammen, K. Bley, P. Papadopoulos, F. Schellenberger, N. Encinas, H. Butt, C. K. Weiss and D. Vollmer, Soft Matter, 2015, 11, 506 DOI: 10.1039/C4SM02216E

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