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Issue 2, 2015
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Platinum-decorated carbon nanotubes for hydrogen oxidation and proton reduction in solid acid electrochemical cells

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Abstract

Pt-decorated carbon nanotubes (Pt-CNTs) were used to enhance proton reduction and hydrogen evolution in solid acid electrochemical cells based on the proton-conducting electrolyte CsH2PO4. The carbon nanotubes served as interconnects to the current collector and as a platform for interaction between the Pt and CsH2PO4, ensuring minimal catalyst isolation and a large number density of active sites. Particle size matching was achieved by using electrospray deposition to form sub-micron to nanometric CsH2PO4. A porous composite electrode was fabricated from electrospray deposition of a solution of Pt-CNTs and CsH2PO4. Using AC impedance spectroscopy and cyclic voltammetry, the total electrode overpotential corresponding to proton reduction and hydrogen oxidation of the most active electrodes containing just 0.014 mg cm−1 of Pt was found to be 0.1 V (or 0.05 V per electrode) at a current density of 42 mA cm−2 for a measurement temperature of 240 °C and a hydrogen-steam atmosphere. The zero bias electrode impedance was 1.2 Ω cm2, corresponding to a Pt utilization of 61 S mg−1, a 3-fold improvement over state-of-the-art electrodes with a 50× decrease in Pt loading.

Graphical abstract: Platinum-decorated carbon nanotubes for hydrogen oxidation and proton reduction in solid acid electrochemical cells

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Publication details

The article was received on 30 Sep 2014, accepted on 10 Dec 2014 and first published on 22 Dec 2014


Article type: Edge Article
DOI: 10.1039/C4SC03003F
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Chem. Sci., 2015,6, 1570-1577
  • Open access: Creative Commons BY-NC license
    All publication charges for this article have been paid for by the Royal Society of Chemistry

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    Platinum-decorated carbon nanotubes for hydrogen oxidation and proton reduction in solid acid electrochemical cells

    V. S. Thoi, R. E. Usiskin and S. M. Haile, Chem. Sci., 2015, 6, 1570
    DOI: 10.1039/C4SC03003F

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