Jump to main content
Jump to site search

Issue 61, 2015
Previous Article Next Article

Tribochemistry of phosphorus additives: experiments and first-principles calculations

Author affiliations

Abstract

Organophosphorus compounds are common additives included in liquid lubricants for many applications, in particular automotive applications. Typically, organic phosphites function as friction-modifiers whereas phosphates as anti-wear additives. While the antiwear action of phosphates is now well understood, the mechanism by which phosphites reduce friction is still not clear. Here we study the tribochemistry of both phosphites and phosphates using gas phase lubrication (GPL) and elucidate the microscopic mechanisms that lead to the better frictional properties of phosphites. In particular, by in situ spectroscopic analysis we show that the friction reduction is connected to the presence of iron phosphide, which is formed by tribochemical reactions involving phosphites. The functionality of elemental phosphorus in reducing the friction of iron-based interfaces is elucidated by first principle calculations. In particular, we show that the work of separation and shear strength of iron dramatically decrease by increasing the phosphorus concentration at the interface. These results suggest that the functionality of phosphites as friction modifiers may be related to the amount of elemental phosphorus that they can release at the tribological interface.

Graphical abstract: Tribochemistry of phosphorus additives: experiments and first-principles calculations

Back to tab navigation

Supplementary files

Publication details

The article was received on 13 Jan 2015, accepted on 21 May 2015 and first published on 22 May 2015


Article type: Paper
DOI: 10.1039/C5RA00721F
Author version
available:
Download author version (PDF)
RSC Adv., 2015,5, 49270-49279

  •   Request permissions

    Tribochemistry of phosphorus additives: experiments and first-principles calculations

    M. I. De Barros-Bouchet, M. C. Righi, D. Philippon, S. Mambingo-Doumbe, T. Le-Mogne, J. M. Martin and A. Bouffet, RSC Adv., 2015, 5, 49270
    DOI: 10.1039/C5RA00721F

Search articles by author

Spotlight

Advertisements