Issue 128, 2015
From the journal:

RSC Advances

Ruthenium/base-catalyzed ortho-selective C–H arylation of acylarenes with halogenated arylboronates†

Tetsuya Yamamoto‡a  and  Tetsu Yamakawa*a  

* Corresponding authors

a Catalysis Group, Sagami Chemical Research Institute, Hayakawa 2743-1, Ayase, Kanagawa 252-1193, Japan
E-mail: t_yamakawa@sagami.or.jp

Abstract

Ruthenium-catalyzed ortho-selective C–H arylation of acylarenes with halogenated aryl-boronates was promoted by the catalytic amount of bases and provided desired halogenated biaryls in excellent yields under 0.2–1 mol% ruthenium catalyst loading.

Graphical abstract: Ruthenium/base-catalyzed ortho-selective C–H arylation of acylarenes with halogenated arylboronates

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Article information

DOI
https://doi.org/10.1039/C5RA19810K
Article type
Paper
Submitted
25 Sep 2015
Accepted
01 Dec 2015
First published
03 Dec 2015

RSC Adv., 2015,5, 105829-105836

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Ruthenium/base-catalyzed ortho-selective C–H arylation of acylarenes with halogenated arylboronates

T. Yamamoto and T. Yamakawa, RSC Adv., 2015, 5, 105829 DOI: 10.1039/C5RA19810K

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