Issue 117, 2015
From the journal:

RSC Advances

Disulfide-based metal-free α-sulfanylation of ketones†

Andrea F. Vaquer,a   Angelo Frongia,a   Francesco Secci*a  and  Enrica Tuveria  

* Corresponding authors

a Dipartimento di Scienze Chimiche e Geologiche, Università degli Studi di Cagliari, Complesso Universitario di Monserrato, S.S. 554, bivio per Sestu, Monserrato, Ca, ITALY
E-mail: fsecci@unica.it
Fax: +39 070 6754388
Tel: +39 070 6754384

Abstract

An eco-friendly methodology for the direct α-sulfanylation of ketones, has been developed. The procedure, based on the use of functionalized diaryldisulfides and catalyzed by D,L-proline, represents a mild and efficient approach for the preparation of α-arylthio-ketones.

Graphical abstract: Disulfide-based metal-free α-sulfanylation of ketones

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Article information

DOI
https://doi.org/10.1039/C5RA17913K
Article type
Paper
Submitted
03 Sep 2015
Accepted
28 Oct 2015
First published
29 Oct 2015

RSC Adv., 2015,5, 96695-96704

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Disulfide-based metal-free α-sulfanylation of ketones

A. F. Vaquer, A. Frongia, F. Secci and E. Tuveri, RSC Adv., 2015, 5, 96695 DOI: 10.1039/C5RA17913K

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