Issue 88, 2015
From the journal:

RSC Advances

Copper-mediated reaction of oxazirconacyclopentenes with dichlorophenylphosphine: a new pathway for the formation of 1,2-oxaphosphole derivatives†

Yiqing Zhou,ab   Sheng Wang,a   Chao Chena  and  Chanjuan Xi*a  

* Corresponding authors

a Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China
E-mail: cjxi@tsinghua.edu.cn

b Beijing National Day School, Beijing 100039, China

Abstract

Copper-mediated reaction of oxazirconacyclopentenes with dichlorophenylphosphine afforded 2,5-dihydro-1,2-oxaphosphole in high yields, in which the reaction was performed conveniently in one-pot from an alkyne, carbonyl compound and dichlorophosphine.

Graphical abstract: Copper-mediated reaction of oxazirconacyclopentenes with dichlorophenylphosphine: a new pathway for the formation of 1,2-oxaphosphole derivatives

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Article information

DOI
https://doi.org/10.1039/C5RA13818C
Article type
Communication
Submitted
14 Jul 2015
Accepted
17 Aug 2015
First published
17 Aug 2015

RSC Adv., 2015,5, 71724-71727

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Copper-mediated reaction of oxazirconacyclopentenes with dichlorophenylphosphine: a new pathway for the formation of 1,2-oxaphosphole derivatives

Y. Zhou, S. Wang, C. Chen and C. Xi, RSC Adv., 2015, 5, 71724 DOI: 10.1039/C5RA13818C

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