Influence of the surface layer of hydrated silicon on the stabilization of Co2+ cations in Zr–Si fiberglass materials according to XPS, UV-Vis DRS, and differential dissolution phase analysis

Abstract

The stabilization of cobalt cations in zirconium–silica fiberglass materials was studied by X-ray photoelectron spectroscopy, ultraviolet visible diffusion reflectance spectroscopy, and a differential dissolution phase analysis. It was found that the commercial Zr–Si fiberglass material contained a layer of hydrated silicon (the depth of 6 nm) on the surface of the glass fibers. Modification of the fiberglass material with cobalt led to its distribution in the fibers mainly in the Co²⁺ state. It was shown that 90% of cobalt was stabilized on the surface and in the hydrated silicon layer as Co²⁺ cations in tetrahedral oxygen coordination, while the remaining 10% was distributed non-uniformly in the bulk of the fibers as Co²⁺ cations in octahedral oxygen coordination.