Issue 67, 2015
From the journal:

RSC Advances

Palladium-catalyzed ligand-free and efficient Suzuki–Miyaura reaction of heteroaryl halides with MIDA boronates in water†

Chun Liu,*a   Xinmin Li,a   Chao Liu,a   Xinnan Wanga  and  Jieshan Qiua  

* Corresponding authors

a State Key Laboratory of Fine Chemicals, Dalian University of Technology, Linggong Road 2, Dalian 116024, China
E-mail: cliu@dlut.edu.cn
Tel: +86-411-84986182

Abstract

A simple and environment-friendly protocol for the palladium-catalyzed ligand-free Suzuki–Miyaura reaction of heteroaryl halides with N-methyliminodiacetic acid (MIDA) boronates is developed. The reaction is performed in water as the sole medium and allows the preparation of a variety of heterobiaryls in excellent yields.

Graphical abstract: Palladium-catalyzed ligand-free and efficient Suzuki–Miyaura reaction of heteroaryl halides with MIDA boronates in water

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Article information

DOI
https://doi.org/10.1039/C5RA10001A
Article type
Communication
Submitted
29 May 2015
Accepted
15 Jun 2015
First published
15 Jun 2015

RSC Adv., 2015,5, 54312-54315

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Palladium-catalyzed ligand-free and efficient Suzuki–Miyaura reaction of heteroaryl halides with MIDA boronates in water

C. Liu, X. Li, C. Liu, X. Wang and J. Qiu, RSC Adv., 2015, 5, 54312 DOI: 10.1039/C5RA10001A

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